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https://dspace.ffh.bg.ac.rs/handle/123456789/952| Title: | The electronic transition moment function of the E<sup>1</sup>Π<inf>u</inf>–X<sup>1</sup>Σ<sup>+</sup><inf>g</inf> system of Ag<inf>2</inf>*<sup>1</sup> | Authors: | Antić-Jovanović, A. Kuzmanović, Miroslav Khakoo, M. A. Laher, R. R. |
Keywords: | Absorption bands;E Π -X Σ system of Ag 1 1 + u g 2;Electronic transition | Issue Date: | 1-Jan-2011 | Journal: | Russian Journal of Physical Chemistry A | Abstract: | Measurement of relative band strengths of 10 absorption bands of the E1Πu–X1 Σ+g system of diatomic silver,107,109Ag2, was performed for the first time. Theoretical analysis of the experimental data, based on Rydberg–Klein–Rees potential energy curves, revealed that assumption of the r-centroid approximation is valid for this system. Comparison of the measured and computed band strength ratios for 5 pairs of bands having common lower levels led to the following linear relative electronic transition moment function for the107,109Ag2 E–X band system: Re(rv'v'') = 2.36rv'v'' – 5.64, in arbitrary units, over the 2.65–2.73 Å range of internuclear distance. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/952 | ISSN: | 0036-0244 | DOI: | 10.1134/S0036024411130024 |
| Appears in Collections: | Journal Article |
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