Experimental and predicted Ag<inf>2</inf> B<inf>1</inf>π<inf>u</inf>-X¹Σ<inf>g</inf>⁺ absorption band strengths

Abstract

Relative intensities in the absorption spectrum of the B1πu-X1Σg+ band system of diatomic silver are measured for the first time. Analysis of these measurements is performed using Rydberg-Klein-Rees potential curves derived from the best available vibrational and rotational constants for this band system. Comparison of measured and calculated absorption band strength ratios for eleven vibrational bands reveals that the relative electronic transition moment function (ETMF) of the Ag2 B-X system has a negative slope and decreases by 40% over the 2.43-2.58range of internuclear distance. The ETMF shows some nonlinear structure; however, the empirical error bars suggest that a linear model is appropriate, thus allowing the r-centroid approximation as a simplification in our analysis. © 2010 Elsevier Ltd.