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https://dspace.ffh.bg.ac.rs/handle/123456789/571| Title: | Alkene-assisted cis-to-trans isomerization of non-conjugated polyunsaturated alkenes | Authors: | Smarun, A V Duzhin, F Petković, Milena Vidović, D |
Issue Date: | 24-Oct-2017 | Journal: | Dalton transactions (Cambridge, England : 2003) | Abstract: | Complex [Cp*Ru(NCMe)3][PF6], 1a, has been identified as a cis-to-trans isomerization catalyst of various non-conjugated cis-polyalkenes under exceptional kinetic control as no alkene conjugation was observed. According to the experimental and theoretical data, the cis-trans isomerization occurred via an alkene-assisted mechanism in which one cis-double bond always served as an anchoring site. Using a combination of multinuclear NMR spectroscopic evidence and mathematical methods it was possible to determine the extent of trans isomerization. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/571 | ISSN: | 1477-9226 | DOI: | 10.1039/c7dt03041j |
| Appears in Collections: | Journal Article |
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