Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/571
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Smarun, A V | en_US |
dc.contributor.author | Duzhin, F | en_US |
dc.contributor.author | Petković, Milena | en_US |
dc.contributor.author | Vidović, D | en_US |
dc.date.accessioned | 2022-12-15T16:13:50Z | - |
dc.date.available | 2022-12-15T16:13:50Z | - |
dc.date.issued | 2017-10-24 | - |
dc.identifier.issn | 1477-9226 | en |
dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/571 | - |
dc.description.abstract | Complex [Cp*Ru(NCMe)3][PF6], 1a, has been identified as a cis-to-trans isomerization catalyst of various non-conjugated cis-polyalkenes under exceptional kinetic control as no alkene conjugation was observed. According to the experimental and theoretical data, the cis-trans isomerization occurred via an alkene-assisted mechanism in which one cis-double bond always served as an anchoring site. Using a combination of multinuclear NMR spectroscopic evidence and mathematical methods it was possible to determine the extent of trans isomerization. | en |
dc.language.iso | en | en |
dc.relation.ispartof | Dalton transactions (Cambridge, England : 2003) | en |
dc.title | Alkene-assisted cis-to-trans isomerization of non-conjugated polyunsaturated alkenes | en_US |
dc.type | Journal Article | en_US |
dc.identifier.doi | 10.1039/c7dt03041j | - |
dc.identifier.pmid | 28991293 | - |
dc.identifier.scopus | 2-s2.0-85032570620 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85032570620 | - |
dc.relation.firstpage | 14244 | en |
dc.relation.lastpage | 14250 | en |
dc.relation.issue | 41 | en |
dc.relation.volume | 46 | en |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
item.languageiso639-1 | en | - |
item.openairetype | Journal Article | - |
crisitem.author.orcid | 0000-0001-6180-1854 | - |
Appears in Collections: | Journal Article |
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