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https://dspace.ffh.bg.ac.rs/handle/123456789/562| Title: | Bis(carbodicarbene)phosphenium trication: the case against hypervalency | Authors: | Đorđević, Nemanja Ganguly, Rakesh Petković, Milena Vidović, Dragoslav |
Issue Date: | 28-Jul-2016 | Journal: | Chemical communications (Cambridge, England) | Abstract: | The first example of a phosphenium trication has been prepared by using the exceptional nucleophilic properties of a carbodicarbene ligand. According to theoretical investigations the trication contains quite polarized P-C bonds suggesting a substantial contribution from the dative bond model. As one of the resonance forms for the title compound depicted a hypervalent phosphoranide we also showed that phosphoranides, in general, do not contain a hypervalent P centre. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/562 | ISSN: | 1359-7345 | DOI: | 10.1039/c6cc04161b |
| Appears in Collections: | Journal Article |
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