Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/562| Title: | Bis(carbodicarbene)phosphenium trication: the case against hypervalency | Authors: | Đorđević, Nemanja Ganguly, Rakesh Petković, Milena Vidović, Dragoslav |
Issue Date: | 28-Jul-2016 | Journal: | Chemical communications (Cambridge, England) | Abstract: | The first example of a phosphenium trication has been prepared by using the exceptional nucleophilic properties of a carbodicarbene ligand. According to theoretical investigations the trication contains quite polarized P-C bonds suggesting a substantial contribution from the dative bond model. As one of the resonance forms for the title compound depicted a hypervalent phosphoranide we also showed that phosphoranides, in general, do not contain a hypervalent P centre. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/562 | ISSN: | 1359-7345 | DOI: | 10.1039/c6cc04161b |
| Appears in Collections: | Journal Article |
Show full item record
SCOPUSTM
Citations
22
checked on Dec 30, 2024
Page view(s)
14
checked on Jan 2, 2025
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.