Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/411| Title: | Nickel-rare earth electrodes for sodium borohydride electrooxidation | Authors: | Santos, D. M.F. Šljukić Paunković, Biljana Amaral, L. Milikić, Jadranka Sequeira, C. A.C. Macciò, D. Saccone, A. |
Keywords: | Borohydride oxidation;Direct borohydride fuel cells;Nickel-rare earth alloys | Issue Date: | 1-Feb-2016 | Journal: | Electrochimica Acta | Abstract: | Binary alloys of nickel (Ni) and dysprosium (Dy) or samarium (Sm) of different composition were prepared. Their electrocatalytic activity in respect to borohydride oxidation in alkaline medium was investigated by cyclic voltammetry, chronoamperometry and chronopotentiometry. It was correlated to their morphological and structural properties examined by SEM/EDXS and XRPD. Ni0.95Dy0.05 alloy electrode showed the highest electrocatalytic activity for BOR, and Ni0.90Sm0.10 showed the lowest. The activity of the rare earth alloys was compared to other Ni- and Pt-based materials, with promising results being reported, which envisage application of these materials as electrodes in direct borohydride fuel cells. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/411 | ISSN: | 0013-4686 | DOI: | 10.1016/j.electacta.2015.12.218 |
| Appears in Collections: | Journal Article |
Show full item record
SCOPUSTM
Citations
45
checked on Jun 2, 2025
Page view(s)
29
checked on Jun 4, 2025
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.