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Please use this identifier to cite or link to this item: https://dspace.ffh.bg.ac.rs/handle/123456789/392
Title: Effect of RTILs on the hydrogen evolution reaction in alkaline media
Authors: Amaral, L.
Cardoso, D. S.P.
Šljukić Paunković, Biljana 
Santos, D. M.F.
Sequeira, C. A.C.
Issue Date: 1-Jan-2016
Journal: ECS Transactions
Abstract: 
Three 1-ethyl-3-methylimidazolium [Emim]-based room temperature ionic liquids (RTILs), namely [Emim][Ac] (acetate), [Emim][EtSO4] (ethylsulfate) and [Emim][MeSO3] (methanesulfonate), were tested as additives in alkaline solutions for hydrogen evolution reaction (HER). Electrochemical measurements were performed with a platinum foil working electrode at 25 °C in 8 M KOH solution and after adding 1-2 vol.% of each ionic liquid. From the polarization curves, Tafel plots were constructed and the main kinetic parameters were obtained for all different electrolytes. Higher currents were found after [Emim][MeSO3] addition. Electrochemical impedance spectroscopy measurements revealed a significant decrease of the overall impedance in the RTILs added electrolytes.
URI: https://dspace.ffh.bg.ac.rs/handle/123456789/392
ISBN: 9781607687504
ISSN: 1938-6737
DOI: 10.1149/07223.0023ecst
Appears in Collections:Conference paper

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University of Belgrade
Faculty of Physical Chemistry
Studentski trg 12-16
11158 Belgrade 118
PAC 105305
SERBIA
University of Belgrade Faculty of Physical Chemistry