Skip navigation
  • Logo
  • Home
  • Communities
    & Collections
  • Research Outputs
  • Researchers
  • Projects
  • Explore by
    • Research Outputs
    • Researchers
    • Projects
  • Sign on to:
    • My DSpace
    • Receive email
      updates
    • Edit Account details
FFH logo

  1. RePhyChem
  2. Research Outputs
  3. Journal Article
Please use this identifier to cite or link to this item: https://dspace.ffh.bg.ac.rs/handle/123456789/314
Title: Reverse intersystem crossing in rhodamines by near-infrared laser excitation
Authors: Marian, Christel M
Etinski, Mihajlo 
Rai-Constapel, Vidisha
Issue Date: 28-Aug-2014
Journal: The journal of physical chemistry. A
Abstract: 
The population of the long-lived first excited triplet state (T1) of a fluorescence dye represents a major limitation in single-molecule spectroscopy. Reverse intersystem crossing (ReISC) is one of the processes that may prevent considerable loss of luminescence. In the present quantum chemical study we have analyzed rhodamine A in aqueous environment. The T2 ⇝ S1 and T3 ⇝ S2 ReISC channels are predicted to be viable. The rate constant computed for the former channel is ≈2 × 10(6) s(-1). Hence, an excitation with suitable wavelength to one of the triplets should help repopulate the optically bright singlet state S1.
URI: https://dspace.ffh.bg.ac.rs/handle/123456789/314
ISSN: 1089-5639
DOI: 10.1021/jp506904v
Appears in Collections:Journal Article

Show full item record

SCOPUSTM   
Citations

11
checked on Jun 11, 2025

Page view(s)

14
checked on Jun 11, 2025

Google ScholarTM

Check

Altmetric

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.


Explore by
  • Communities
    & Collections
  • Research Outputs
  • Researchers
  • Projects
University of Belgrade
Faculty of Physical Chemistry
Studentski trg 12-16
11158 Belgrade 118
PAC 105305
SERBIA
University of Belgrade Faculty of Physical Chemistry