Study of Graphene Oxide and Silver Nanowires Interactions and Its Association with Electromagnetic Shielding Effectiveness

Abstract

Technological development has led to the need for materials able to block electromagnetic waves (EMWs) emitted from various devices. EMWs could negatively affect the working performance and lifetime of multiple instruments and measuring devices. New EMW shielding materials are being developed, while among nanomaterials, graphene-based composites have shown promising features. Herein, we have produced graphene oxide (GO), silver nanowires (AgNWs) composites, by varying the mass ratios of each component. UV-Vis, infrared, Raman spectroscopies, and thermogravimetric analysis proved the establishment of the interactions between them. For the first time, the strength and the nature of the interaction between GO sheets with various levels of oxidation and AgNWs were investigated using density function theory (DFT). The interaction energy between ideal graphene and AgNWs was calculated to be −48.9 kcal/mol, while for AgNWs and GO, this energy is almost doubled at −81.9 kcal/mol. The DFT results confirmed the interfacial polarization at the heterointerface via charge transfer and accumulation at the interface, improving the efficacy of EMW shielding. Our results indicated that AgNWs create a compact complex with GO due to charge transfer between them. Charge redistributions in GO-AgNWs composites resulted in an improved ability of the composite to block EMWs compared to GO alone.