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Title: | A potential source of free radicals in iodine-based chemical oscillators | Authors: | Stanisavljev, Dragomir Milenković, Maja C Mojović, Miloš Popović Bijelić, Ana |
Issue Date: | 24-Mar-2011 | Journal: | The journal of physical chemistry. A | Abstract: | The iodide-peroxide system in an acidic medium was investigated as a potential source of free radicals in iodine-based chemical oscillators. The radicals were detected by EPR spin-trapping using spin-trap 5-(tert-butoxycarbonyl)-5-methyl-1-pyrroline N-oxide (BMPO), which forms stable spin-adducts with oxygen-centered radicals. The iodide-peroxide system is introduced as an easily available laboratory source of free radicals. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/201 | ISSN: | 1089-5639 | DOI: | 10.1021/jp200837u |
Appears in Collections: | Journal Article |
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