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Title: | Thermally induced phase transformation of Pb-exchanged LTA and FAU-framework zeolite to feldspar phases | Authors: | Radosavljevic-Mihajlovic, A. S. Kremenovic, A. S. Dosen, A. M. Andrejic, J. Z. Dondur, Vera |
Keywords: | Microstructure;Pb-feldspar FAU;Pb-feldspar LTA;Rietveld method;Thermally induced transformation | Issue Date: | 1-Jul-2015 | Journal: | Microporous and Mesoporous Materials | Abstract: | Thermally induced phase transformations of Pb-exchange LTA and FAU zeolites were from ambient temperature to 1300 °C. Both frameworks collapse into amorphous intermediate products after heating between 600 and 650 °C. Prolonged heating of the intermediate product over 1100 °C results in the formation of disordered Pb-feldsparLTA [a = 8.414 (4) Å, b = 13.048 (4) Å, c = 7.169 (4) Å, β = 115.35° (3)] and Pb-feldsparFAU [a = 8.422 (4) Å, b = 13.054 (4) Å, c = 7.173 (4) Å, β = 115.37° (3)] phases. The phase conversions within the investigated temperature range were followed by thermal (DTA, TGA, and DSC), XRPD, and Raman methods. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/1626 | ISSN: | 1387-1811 | DOI: | 10.1016/j.micromeso.2014.08.059 |
Appears in Collections: | Journal Article |
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