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Please use this identifier to cite or link to this item: https://dspace.ffh.bg.ac.rs/handle/123456789/1594
Title: Room-temperature interaction of n-hexane with ZSM-5 zeolites : Microcalorimetric and temperature-programmed desorption studies
Authors: Rac, V.
Rakić, Vesna
Gajinov, S.
Dondur, Vera
Auroux, Aline
Keywords: Microcalorimetry;n-hexane;Temperature-programmed desorption;ZSM-5
Issue Date: 1-Jan-2006
Journal: Journal of Thermal Analysis and Calorimetry
Abstract: 
In this work, room temperature interaction of n-hexane with HZSM-5 (Si/Al=20) and ion-exchanged samples containing one (CuZSM-5, FeZSM-5 and MnZSM-5) or two transition-metal cations (Fe,CuZSM-5; Cu,MnZSM-5 and Fe,MnZSM-5) was studied by microcalorimetry and TPD methods. Both differential heats and the amounts of n-hexane adsorbed per one unit cell were quantitatively determined. Higher heats of adsorption and higher amounts of adsorbed gas were found for ion-exchanged samples than for HZSM-5. The experiments of n-hexane adsorption on hydrated samples were also performed. The amounts of n-hexane adsorbed on hydrated ZSM-5 were lower in comparison with dehydrated samples, while the energies of interaction were similar. © 2006 Akadémiai Kiadó.
URI: https://dspace.ffh.bg.ac.rs/handle/123456789/1594
ISSN: 1388-6150
DOI: 10.1007/s10973-005-7164-z
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University of Belgrade
Faculty of Physical Chemistry
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11158 Belgrade 118
PAC 105305
SERBIA
University of Belgrade Faculty of Physical Chemistry