Ab initio calculation of the potential surfaces and the electronic transition moments for the valence and Rydberg doublet electronic states of HCO

Abstract

Results of large-scale configuration interaction calculations of the bending and C-O stretching potential curves and the corresponding electric transition moments for the low lying doublet electronic states of HCO are presented. Special attention is paid to the study of interaction between valence- and Rydberg-type species. © 1993 American Institute of Physics.