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https://dspace.ffh.bg.ac.rs/handle/123456789/1215| Title: | Isokinetic parameters of thermal degradation of powder of [Cd(N-Boc-gly)<inf>2</inf>(H<inf>2</inf>O)<inf>2</inf>]<inf>n</inf> | Authors: | Begović, N. Vasić, Milica Grković, A. Blagojević, V. A. Minić, Dragica |
Keywords: | Coordination polymer;Isokinetic temperature;Kinetic parameters;Resonant vibrational frequency | Issue Date: | 1-Jan-2014 | Journal: | Science of Sintering | Abstract: | The coordination polymer [Cd(N-Boc-gly)2(H2O)2]n undergoes thermally induced degradation in temperature region between 60 and 900oC. Kinetic parameters were determined for dehydration (63-123oC) and further degradation processes (123-461oC) using different isoconversional and non-isoconversional methods. Due to appearance of kinetic “compensation effect”, isokinetic temperatures were determined for individual degradation processes and correlated with resonant vibrational frequencies ascribed to Cd-OH2 coordination bond, Cd-O (O from N-Boc-glyH ligand) coordination bond and C-O covalent bond. |
URI: | https://dspace.ffh.bg.ac.rs/handle/123456789/1215 | ISSN: | 0350-820X | DOI: | 10.2298/SOS1403323B |
| Appears in Collections: | Journal Article |
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