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Please use this identifier to cite or link to this item: https://dspace.ffh.bg.ac.rs/handle/123456789/837
DC FieldValueLanguage
dc.contributor.authorRadulović, Aleksandraen_US
dc.contributor.authorDondur, Veraen_US
dc.contributor.authorVulić, Predragen_US
dc.contributor.authorMiladinović, Zoranen_US
dc.contributor.authorĆirić-Marjanović, Gordanaen_US
dc.contributor.authorDimitrijević, Radovanen_US
dc.date.accessioned2022-12-15T17:18:21Z-
dc.date.available2022-12-15T17:18:21Z-
dc.date.issued2013-09-01-
dc.identifier.issn0022-3697en
dc.identifier.urihttps://dspace.ffh.bg.ac.rs/handle/123456789/837-
dc.description.abstractIn this work we investigated the conditions under which pure basic hexagonal nepheline phase is formed by the zeolite Na-LTA thermal transformation route. The influence of small variations in Na-LTA bulk stoichiometry on the rate and course of the thermal transformation process was examined. The starting materials were three Na-LTA samples with different Na2O: Al 2O3: SiO2 ratios: 0.99Na2O: 1.00Al2O3: 2.00 SiO2, 1.05Na2O: 1.06Al2O3: 2.00SiO2 and 1.05Na2O: 1.00Al2O3: 2.05SiO2. Upon heat treatment, the zeolite samples showed different conversion routes. At temperatures above 950 C all three Na-LTA samples transformed into nepheline-type polymorphs. While the Na-LTA sample with the composition close to ideal stoichiometry gave pure basic hexagonal nepheline, the Na-LTA samples containing sodium, aluminum and silica excess formed mixtures of basic hexagonal nepheline and monoclinic trinepheline. The synthesized nepheline-type polymorphs were investigated by X-ray powder diffraction, Raman and NMR spectroscopy. © 2013 Elsevier Ltd.en
dc.relation.ispartofJournal of Physics and Chemistry of Solidsen
dc.subjectA. Ceramicsen
dc.subjectC. Raman spectroscopyen
dc.subjectC. X-ray diffractionen
dc.subjectD. Nuclear magnetic resonance (NMR)en
dc.subjectD. Phase transitionsen
dc.titleRoutes of synthesis of nepheline-type polymorphs: An influence of Na-LTA bulk composition on its thermal transformationsen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.jpcs.2013.03.019-
dc.identifier.scopus2-s2.0-84878305075-
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/84878305075-
dc.relation.firstpage1212en
dc.relation.lastpage1220en
dc.relation.issue9en
dc.relation.volume74en
item.fulltextNo Fulltext-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
crisitem.author.orcid0000-0003-3507-3966-
crisitem.author.orcid0000-0002-1050-7003-
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University of Belgrade
Faculty of Physical Chemistry
Studentski trg 12-16
11158 Belgrade 118
PAC 105305
SERBIA
University of Belgrade Faculty of Physical Chemistry