Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/576| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Biliškov, Nikola | en_US |
| dc.contributor.author | Novak, Jurica | en_US |
| dc.contributor.author | Petković, Milena | en_US |
| dc.contributor.author | Zgrablić, Goran | en_US |
| dc.contributor.author | Baranović, Goran | en_US |
| dc.contributor.author | Došlić, Nada | en_US |
| dc.date.accessioned | 2022-12-15T16:13:51Z | - |
| dc.date.available | 2022-12-15T16:13:51Z | - |
| dc.date.issued | 2011-10-01 | - |
| dc.identifier.issn | 0011-1643 | en |
| dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/576 | - |
| dc.description.abstract | The vibrational spectra of the protonated Schiff base of n-butylretinal (nSBR+) in dichloromethane are studied. The trifluoroacetic acid (TFA) is used for the protonation of the Schiff base of nbutylretinal (nSBR). Combining the two-dimensional correlation analysis of the experimental infrared spectra with anharmonic frequency calculations it is shown that two types of ionic aggregates between nSBR+ and the TFA counterion are formed. The study suggests that the interaction between nSBR+ and the TFA counterion may be responsible for the observed lost of photoselectivity in the trans-cis isomerization of the nSBR+ in solution. | en |
| dc.relation.ispartof | Croatica Chemica Acta | en |
| dc.subject | Anharmonic frequency | en |
| dc.subject | DFT | en |
| dc.subject | Hydrogen bonding | en |
| dc.subject | Infrared spectroscopy | en |
| dc.subject | n-butylretinal | en |
| dc.subject | Trifluoroacetic acid | en |
| dc.title | Localization of the counterion of the protonated schiff base of n-butylretinal in solution | en_US |
| dc.type | Article | en_US |
| dc.identifier.doi | 10.5562/cca1826 | - |
| dc.identifier.scopus | 2-s2.0-80054121515 | - |
| dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/80054121515 | - |
| dc.relation.firstpage | 221 | en |
| dc.relation.lastpage | 231 | en |
| dc.relation.issue | 2 | en |
| dc.relation.volume | 84 | en |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.cerifentitytype | Publications | - |
| item.fulltext | No Fulltext | - |
| item.openairetype | Article | - |
| item.grantfulltext | none | - |
| crisitem.author.orcid | 0000-0001-6180-1854 | - |
| Appears in Collections: | Journal Article | |
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