Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/576| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Biliškov, Nikola | en_US |
| dc.contributor.author | Novak, Jurica | en_US |
| dc.contributor.author | Petković, Milena | en_US |
| dc.contributor.author | Zgrablić, Goran | en_US |
| dc.contributor.author | Baranović, Goran | en_US |
| dc.contributor.author | Došlić, Nada | en_US |
| dc.date.accessioned | 2022-12-15T16:13:51Z | - |
| dc.date.available | 2022-12-15T16:13:51Z | - |
| dc.date.issued | 2011-10-01 | - |
| dc.identifier.issn | 0011-1643 | en |
| dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/576 | - |
| dc.description.abstract | The vibrational spectra of the protonated Schiff base of n-butylretinal (nSBR+) in dichloromethane are studied. The trifluoroacetic acid (TFA) is used for the protonation of the Schiff base of nbutylretinal (nSBR). Combining the two-dimensional correlation analysis of the experimental infrared spectra with anharmonic frequency calculations it is shown that two types of ionic aggregates between nSBR+ and the TFA counterion are formed. The study suggests that the interaction between nSBR+ and the TFA counterion may be responsible for the observed lost of photoselectivity in the trans-cis isomerization of the nSBR+ in solution. | en |
| dc.relation.ispartof | Croatica Chemica Acta | en |
| dc.subject | Anharmonic frequency | en |
| dc.subject | DFT | en |
| dc.subject | Hydrogen bonding | en |
| dc.subject | Infrared spectroscopy | en |
| dc.subject | n-butylretinal | en |
| dc.subject | Trifluoroacetic acid | en |
| dc.title | Localization of the counterion of the protonated schiff base of n-butylretinal in solution | en_US |
| dc.type | Article | en_US |
| dc.identifier.doi | 10.5562/cca1826 | - |
| dc.identifier.scopus | 2-s2.0-80054121515 | - |
| dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/80054121515 | - |
| dc.relation.firstpage | 221 | en |
| dc.relation.lastpage | 231 | en |
| dc.relation.issue | 2 | en |
| dc.relation.volume | 84 | en |
| item.fulltext | No Fulltext | - |
| item.grantfulltext | none | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.openairetype | Article | - |
| item.cerifentitytype | Publications | - |
| crisitem.author.orcid | 0000-0001-6180-1854 | - |
| Appears in Collections: | Journal Article | |
SCOPUSTM
Citations
5
checked on Jan 1, 2025
Page view(s)
14
checked on Jan 6, 2025
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.