![FFH logo](/image/logo_ffh.png)
Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/531
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Đorđević, Nemanja | en_US |
dc.contributor.author | Tay, Madelyn Qin Yi | en_US |
dc.contributor.author | Muthaiah, Senthilkumar | en_US |
dc.contributor.author | Ganguly, Rakesh | en_US |
dc.contributor.author | Dimić, Dušan | en_US |
dc.contributor.author | Vidović, Dragoslav | en_US |
dc.date.accessioned | 2022-12-15T16:09:26Z | - |
dc.date.available | 2022-12-15T16:09:26Z | - |
dc.date.issued | 2015-05-04 | - |
dc.identifier.issn | 0020-1669 | en |
dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/531 | - |
dc.description.abstract | C-F bond cleavage by transient phosphorus(III)-based dications [RP(C(PPh3)2)](2+) (4a(2+), R = Ph; 4b(2+), R = 4-F-Ph) is reported. These dications were generated by reaction of the corresponding monocationic precursors with excess Na[BAr4(Cl)]. Evidence for the existence of transient dicationic species was obtained by trapping the dication 4a(2+) with PMe3. According to theoretical analysis, the low-lying lowest unoccupied molecular orbitals of these species were responsible for the observed activation of C-F bonds. | en |
dc.language.iso | en | en |
dc.relation.ispartof | Inorganic chemistry | en |
dc.title | C-F bond activation by transient phosphenium dications | en_US |
dc.type | Journal Article | en_US |
dc.identifier.doi | 10.1021/ic5031125 | - |
dc.identifier.pmid | 25871630 | - |
dc.identifier.scopus | 2-s2.0-84929192726 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/84929192726 | - |
dc.relation.firstpage | 4180 | en |
dc.relation.lastpage | 4182 | en |
dc.relation.issue | 9 | en |
dc.relation.volume | 54 | en |
item.openairetype | Journal Article | - |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.orcid | 0000-0001-8127-5396 | - |
Appears in Collections: | Journal Article |
SCOPUSTM
Citations
19
checked on Jun 28, 2024
Page view(s)
8
checked on Jul 4, 2024
Google ScholarTM
Check
Altmetric
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.