Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/2223| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Milikić, Jadranka | en_US |
| dc.contributor.author | Stamenović, Una | en_US |
| dc.contributor.author | Vodnik, Vesna | en_US |
| dc.contributor.author | Otoničar, Mojca | en_US |
| dc.contributor.author | Škapin, Srečo | en_US |
| dc.contributor.author | Šljukić Paunković, Biljana | en_US |
| dc.date.accessioned | 2024-01-15T09:12:29Z | - |
| dc.date.available | 2024-01-15T09:12:29Z | - |
| dc.date.issued | 2023-08-01 | - |
| dc.identifier.issn | 24688231 | - |
| dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/2223 | - |
| dc.description.abstract | The catalytic activity of five silver-polyaniline-polyvinylpyrrolidone (Ag@PANI@PVP1–5) nanocomposites for borohydride oxidation reaction (BOR) was thoroughly examined. The nanocomposites were synthesized by an in situ chemical oxidative polymerization of aniline monomer by Ag+ ions in the presence of accelerator – PVP and physicochemical properties were determined prior their use in electrocatalysis. Ag@PANI@PVP3 with 35.4 wt% Ag delivered the highest current density and specific current density during BOR. Evaluation of the order of reaction < 1 suggested indirect BOR mechanism. Furthermore, Ag@PANI@PVP3 also delivered the highest current density and stable performance during chronoamperometric study of BOR. Its apparent activation energy of 15 kJ mol−1 was found to be the lowest among the studied materials accounting for the high current densities. | en_US |
| dc.relation.ispartof | Molecular Catalysis | en_US |
| dc.subject | Borohydride oxidation reaction | en_US |
| dc.subject | Direct borohydride fuel cell | en_US |
| dc.subject | Polyaniline | en_US |
| dc.subject | Polyvinylpyrrolidone | en_US |
| dc.subject | Silver | en_US |
| dc.title | Combining silver, polyaniline and polyvinylpyrrolidone for efficient electrocatalysis of borohydride oxidation reaction | en_US |
| dc.type | Article | en_US |
| dc.identifier.doi | 10.1016/j.mcat.2023.113310 | - |
| dc.identifier.scopus | 2-s2.0-85162950296 | - |
| dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85162950296 | - |
| dc.relation.volume | 547 | en_US |
| item.fulltext | No Fulltext | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.grantfulltext | none | - |
| item.openairetype | Article | - |
| item.cerifentitytype | Publications | - |
| crisitem.author.orcid | 0000-0003-2266-6738 | - |
| crisitem.author.orcid | 0000-0003-0203-4012 | - |
| Appears in Collections: | Journal Article | |
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