Please use this identifier to cite or link to this item:
https://dspace.ffh.bg.ac.rs/handle/123456789/1953| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Sovilj, Sofija P. | en_US |
| dc.contributor.author | Babić-Samardžija, Ksenija | en_US |
| dc.contributor.author | Minić, Dragica | en_US |
| dc.date.accessioned | 2022-12-21T16:59:47Z | - |
| dc.date.available | 2022-12-21T16:59:47Z | - |
| dc.date.issued | 1998-01-01 | - |
| dc.identifier.issn | 0352-5139 | en |
| dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/1953 | - |
| dc.description.abstract | A new cobalt(III) complex cis-[Co(acac)cyclam](ClO4)2 (cyclam = 1,4,8,11-tetraazacyclotetradecane, acac = 2,4-pentanedionc ion) has been synthesized and characterized by elemental analysis, IR, electronic, 1H- and 13C-NMR and mass spectroscopy. Thermal decomposition studies were also performed and the thermal stability region determined. The spectroscopic data are consistent with a folded conformation of the macrocycle around the cobalt atom, which is hexa-coordinated in a distorted octahedral arrangement. The acac ion joins symmetrically through both the oxygen atoms, the two remaining sites at the cobalt atom acting as a bidentate ligand. | en |
| dc.relation.ispartof | Journal of the Serbian Chemical Society | en |
| dc.subject | Acetylacetonate | en |
| dc.subject | Cobalt(III) | en |
| dc.subject | Complexes | en |
| dc.subject | Cyclam | en |
| dc.subject | Synthesis | en |
| dc.title | Synthesis and physicochemical characterization of the complex cis-[Co(acac)cyclam](ClO<inf>4</inf>)<inf>2</inf> | en_US |
| dc.type | Article | en_US |
| dc.identifier.scopus | 2-s2.0-0038854978 | - |
| dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/0038854978 | - |
| dc.relation.firstpage | 979 | en |
| dc.relation.lastpage | 985 | en |
| dc.relation.issue | 12 | en |
| dc.relation.volume | 63 | en |
| item.fulltext | No Fulltext | - |
| item.grantfulltext | none | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.openairetype | Article | - |
| item.cerifentitytype | Publications | - |
| crisitem.author.orcid | 0000-0001-5055-2039 | - |
| Appears in Collections: | Journal Article | |
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