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https://dspace.ffh.bg.ac.rs/handle/123456789/1573
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Šašić, S. | en_US |
dc.contributor.author | Antić-Jovanović, Ankica | en_US |
dc.contributor.author | Jeremić, M. | en_US |
dc.date.accessioned | 2022-12-21T16:03:08Z | - |
dc.date.available | 2022-12-21T16:03:08Z | - |
dc.date.issued | 1998-11-07 | - |
dc.identifier.issn | 0956-5000 | en |
dc.identifier.uri | https://dspace.ffh.bg.ac.rs/handle/123456789/1573 | - |
dc.description.abstract | Using Raman spectra and factor analysis, the equilibria of mercury(II) thiocyanate complexes in N,N-dimethylformamide solutions with SCN-/Hg(II) molar ratios ranging from 0.6 to 4.0 have been investigated. The spectra were recorded in the region of the ν(Hg-S) and ν(C-N) vibrations. In the former, the Raman bands belonging to four complex species, Hg(SCN)+, Hg(SCN)2, Hg(SCN)3- and Hg(SCN)42-, have been extracted by applying principal component analysis to the spectra. Three components were found in the ν(C-N) region. The concentration of the identified complex species in all investigated solutions has been determined by a target factor analysis method and the disproportionation constants of Hg(SCN)+ and Hg(SCN)3- have been estimated to be 0.18 and 0.21, respectively. | en |
dc.relation.ispartof | Journal of the Chemical Society - Faraday Transactions | en |
dc.title | An investigation of the equilibrium of mercury(II) thiocyanate complexes in DMF solutions via Raman spectra and factor analysis | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1039/a805192e | - |
dc.identifier.scopus | 2-s2.0-33748728491 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/33748728491 | - |
dc.relation.firstpage | 3255 | en |
dc.relation.lastpage | 3260 | en |
dc.relation.issue | 21 | en |
dc.relation.volume | 94 | en |
item.openairetype | Article | - |
item.fulltext | No Fulltext | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.orcid | 0000-0002-9047-8870 | - |
Appears in Collections: | Journal Article |
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