The synthesis of single phase WC nanoparticles/C composite by solid state reaction involving nitrogen-rich carbonized polyaniline

Abstract

Single phase tungsten carbide nanoparticles (WC-NPs), (mean particle diameter 5.4 nm), distributed over carbonized polyaniline (C-PANI) nanotubes/nanosheets were synthesized by a solid state reaction between WO 3 and nitrogen-rich carbonized polyaniline at 1000 C in a reducing atmosphere. The resulting composite was characterized by X-ray diffractometry, electron microscopy, thermogravimetry in oxidizing and reduction atmospheres and elemental analysis. We suggested that the synthesis of WC as a single phase was facilitated by reactive C atoms with dangling bonds, formed upon nitrogen removal. © 2013 Elsevier Ltd and Techna Group S.r.l.