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Please use this identifier to cite or link to this item: https://dspace.ffh.bg.ac.rs/handle/123456789/1224
DC FieldValueLanguage
dc.contributor.authorBegović, Nebojša N.en_US
dc.contributor.authorVasić, Milicaen_US
dc.contributor.authorBlagojević, Vladimir A.en_US
dc.contributor.authorFilipović, Nenad R.en_US
dc.contributor.authorMarinković, Aleksandar D.en_US
dc.contributor.authorMalešević, Aleksandaren_US
dc.contributor.authorMinić, Dragicaen_US
dc.date.accessioned2022-12-16T17:40:13Z-
dc.date.available2022-12-16T17:40:13Z-
dc.date.issued2017-11-01-
dc.identifier.issn1388-6150en
dc.identifier.urihttps://dspace.ffh.bg.ac.rs/handle/123456789/1224-
dc.description.abstractThe structure of new cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-κ2N]-palladium(II) complex was determined using a combination of XRD and IR measurements and DFT calculations. Inherent flexibility of its structure is evident from the complexity of its IR spectrum, which could only be theoretically reproduced as a combination of several closely related structures, involving rotation around C–O bond and changes in hydrogen interactions of its –OH group. Its thermal stability and decomposition were studied non-isothermally, and the thermal decomposition mechanism was proposed using correlation with DFT calculations at the molecular level. It was determined that the initial degradation step consists of the release of Cl free radical, which then reacts with both the initial compound and the degradation products. Besides the endothermic steps, there are exothermic ones, contributing to the complex shape of the DSC curve, consisted of overlapping endothermic and exothermic peaks. Deconvolution of DTG curve allowed identification of primary fragments of the initial degradation process and, in conjunction with DFT calculations, construction of the most likely reaction mechanism.en
dc.relation.ispartofJournal of Thermal Analysis and Calorimetryen
dc.subjectDFT calculationen
dc.subjectOrganometallic complexen
dc.subjectReaction kineticsen
dc.subjectReaction mechanismen
dc.subjectThermal decompositionen
dc.subjectThermodynamicsen
dc.titleSynthesis and thermal stability of cis-dichloro[(E)-ethyl-2-(2-((8-hydroxyquinolin-2-il)methylene)hidrazinyl)acetate-κ<sup>2</sup> N]-palladium(II) complexen_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1007/s10973-017-6458-2-
dc.identifier.scopus2-s2.0-85020119946-
dc.identifier.urlhttps://api.elsevier.com/content/abstract/scopus_id/85020119946-
dc.relation.firstpage701en
dc.relation.lastpage711en
dc.relation.issue2en
dc.relation.volume130en
item.fulltextNo Fulltext-
item.openairetypeJournal Article-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextnone-
item.cerifentitytypePublications-
crisitem.author.orcid0000-0001-5410-580X-
crisitem.author.orcid0000-0001-5055-2039-
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University of Belgrade
Faculty of Physical Chemistry
Studentski trg 12-16
11158 Belgrade 118
PAC 105305
SERBIA
University of Belgrade Faculty of Physical Chemistry